Friday, 9 February 2018

GCSE OCR Gateway Organic Chemistry C6.2h The Structure of Starch and Cellulose

C6.2h  To be able to recall that DNA is a polymer made from four different monomers called nucleotides and that other important naturally-occurring polymers are based on sugars and amino-acids

Naturally occurring polymers based on sugars: Starch and Cellulose

Polymers based on sugars: Starch and cellulose

Starch and cellulose are two naturally occurring polymers that have sugar molecules as their monomer.

They can be drawn simply as polymers of glucose units bonded to each other by an ether —O— linkage. 

Cellulose
This is the cellulose structure:






Starch
Starch is more complicated because it is composed of two different polymers amylose and amylopectin.

Amylose has this structure where the glucose units are linked 1,4 between monomers.  As a result amylose curls up into a spiral structure where as cellulose is a long stranded molecule.




Amylopectin has a branched structure and this means the entire molecule is more open and water soluble.





 



Here is a table summarising the different naturally occurring polysaccharide polymers:


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